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Q. Which of the following does not/do not represent the correct equivalent mass of $Cr_{2}O_{7}^{2-}$ in the reaction
$Cr_{2}O_{7}^{2-}+14H^{+}+6e^{-} \rightarrow 2Cr^{3+}+7H_{2}O $ ?

UPSEEUPSEE 2011

Solution:

image

$\therefore E_{ Cr _{2} O _{7}^{2-}}=\frac{{ }^{M} Cr _{2} O _{7}^{2-}}{6}$

${\left[ Cr _{2}^{6+} \longrightarrow 2 Cr ^{3+}+6 e^{-}\right]}$