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Q. When a system is taken from state $ i $ to state $ f $ along the path $ iaf $ , it is found that $ Q = 50 $ cal and $ W = 20 $ cal. Along path $ibf\, Q = 36 $ cal. $ W $ along the path $ ibf $ is
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UPSEEUPSEE 2010Thermodynamics

Solution:

From first law of thermodynamics,
$Q=\Delta U+W$
For path $iaf$,
$50=\Delta U+20$
$\therefore \Delta U= U_{f}-U_{i}=30\, cal$
For path $i b f$,
$Q=\Delta U+W$
or $W=Q-\Delta U$
$=36-30=6\, cal$