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Q. Total number of geometrical isomers shown by compounds (A) is__________.Chemistry Question Image

Organic Chemistry – Some Basic Principles and Techniques

Solution:

In this case, terminal groups are same.
No. of double bonds n=2.
No. of G.I.=2n1+2n/21
=21+20=3
Following are the 3 structures:
image
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But (iii) and (iv) are same structures. Hence, 3 geometrical isomers are possible.