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Q. The rate constant for forward and backward reaction of hydrolysis of ester are $1.1 \times 10^{-2}$ and $1.5 \times 10^{-3}$ per minute respectively. Equilibrium constant for the reaction $CH _3 COOC _2 H _5+ H ^{+} \rightleftharpoons CH _3 COOH + C _2 H _5 OH$ is

Equilibrium

Solution:

Rate constant of forward reaction $(K)=1.1 \times 10^{-2}$ and rate constant of backward reaction $\left(K_b\right)=1.5 \times 10^{-3}$ per minute.
Equilibrium constant $\left(K_c\right)=\frac{K_f}{K_b}=\frac{1.1 \times 10^{-2}}{1.5 \times 10^{-3}}=7.33$