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Chemistry
The order of ka values of the following acids is :- <img class=img-fluid question-image alt=Question src=https://cdn.tardigrade.in/q/nta/c-zxk96uy7fees.png />
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Q. The order of ka values of the following acids is :-
NTA Abhyas
NTA Abhyas 2020
Organic Chemistry – Some Basic Principles and Techniques
A
(i) > (iv) > (iii) > (iv)
8%
B
(iv) > (i) > (iii) > (ii)
65%
C
(iii) > (iv) > (i) > (ii)
16%
D
(iv) > (i) > (ii) > (iii)
11%
Solution:
$\text{Ka} \, \propto \, \text{Acidity}$
$\text{(iv)}$ is most acidic as its conjugate base is stabilized by the two $- \text{OH}$ groups by intra-molecular $\text{H}$ -bonding.
$\text{(ii)}$ is least acidic as conjugate base is not stabiilized by $\text{H}$ -bond.