Q. The geometry of $ {{[Cu{{(N{{H}_{3}})}_{4}}]}^{2+}} $ ion is:
JIPMERJIPMER 1998
Solution:
$ {}_{29}Cu=1{{s}^{2}},2{{s}^{2}}2{{p}^{6}},3{{s}^{2}}3{{p}^{6}}3{{d}^{10}},4{{s}^{1}} $ $ C{{u}^{2+}}=[Ar]\,3{{d}^{9}},4{{s}^{0}}4{{p}^{0}} $
Hence, geometry of $ {{[Cu{{(N{{H}_{3}})}_{4}}]}^{2+}} $ ion is square-planar and it is paramagnetic ion, as it has one unpaired electron.
