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Q. Standard electrode potentials for $Fe $ electrode are given as
$Fe^{2+}+2e^{-} \rightarrow Fe ; E^{o}=-0.44\, V$
$Fe^{3+}+e^{-} \rightarrow Fe^{2+}; E^{o}=+0.77\, V$
$ Fe^{2+}, Fe^{3+}$ and $Fe$ blocks are kept together then

AIPMTAIPMT 2001Electrochemistry

Solution:

The metals have higher negative values of their electrode potential can displace metals having lower values from their salt solution. So, $Fe ^{3+}$ decreases.