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Q. List I describes thermodynamic processes in four different systems. List II gives the magnitudes (either exactly or as a close approximation) of possible changes in the internal energy of the system due to the process.
List I List II
I $10^{-3} kg$ of water at $100^{\circ} C$ is converted to steam at the same temperature, at a pressure of $10^5 Pa$. The volume of the system changes from $10^{-6} m ^3$ to $10^{-3} m ^3$ in the process. Latent heat of water $=2250 kJ / kg$. P 2 KJ
II $0.2$ moles of a rigid diatomic ideal gas with volume $V$ at temperature $500 K$ undergoes an isobaric expansion to volume $3 V$. Assume $R=8.0 Jmol ^{-1} K ^{-1}$. Q 7 KJ
III On mole of a monatomic ideal gas is compressed adiabatically from volume $V=\frac{1}{3} m ^3$ and pressure $2 kPa$ to volume $\frac{v}{8}$ R 4 KJ
IV Three moles of a diatomic ideal gas whose molecules can vibrate, is given $9 kJ$ of heat and undergoes isobaric expansion. S 5 KJ
T 3 KJ
Which one of the following options is correct?

JEE AdvancedJEE Advanced 2022

Solution:

(I) $ \Delta U =\Delta Q -\Delta W$
$=\left\{\left(10^{-3} \times 2250\right)-\frac{10^5\left(10^{-3}-10^{-6}\right)}{10^3}\right\} kJ $
$ =(2.25-0.0999) kJ$
$=(2.1501) \,kJ $
(II) $ \Delta U = nC _{ V } \Delta T $
$ =\frac{5}{2} nR \Delta T$
$ =\frac{5}{2} \cdot(0.2)(8)(1500-500) J $
$ =4 \,kJ $
(III) $ P_1 V_2^\gamma=P_2 V_2^\gamma $
$ \Rightarrow 2\left(\frac{1}{3}\right)^{5 / 3}=P_2\left(\frac{1}{24}\right)^{5 / 3} $
$\Rightarrow P_2=64 \, k \,Pa$
$ \Delta U=n_{ v } \Delta T =\frac{3}{2} \cdot\left( P _2 V _2- P _1 V _1\right) $
$ =\frac{3}{2}\left(64 \times \frac{1}{24}-2 \times \frac{1}{3}\right) kJ $
$ =3 \, kJ $
(IV) $ \Delta U = nC _{ V } \Delta T$
$ = n \cdot \frac{7}{2} R \Delta T$
$ =\frac{7}{9} \Delta Q $
$ =7 \, kJ$