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Q. Correct order of bond angles for the following is

Odisha JEEOdisha JEE 2009Chemical Bonding and Molecular Structure

Solution:

BCI$_3$ is trigonal in shape where bond angle is 120$^{\circ}$. In NH$_3$ and PCI$_3$ (both are having pyramidal geometry), though the central atom has equal number of Ione pairs \and bond pairs, the valence shell of P is relatively bigger and pond angle is Iower.