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  4. Aniline reacts with excess Br2/H2O to give the major product.

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Q. Aniline reacts with excess $Br_2/H_2O$ to give the major product.

KVPYKVPY 2014Amines

Solution:

Aniline reacts with excess $Br_2/H_2O$ to give $2, 4, 6-$ tribromoaniline as a major product. The $NH_2$ group attached to benzene ring makes it more activating and occupy all the ortho and para positions.
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