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Q. A thermodynamic system is taken from an initial state $i$ with internal energy $U _{ i }=100 \,J$ to the final state $f$ along two different paths iaf and $ibf$, as schematically shown in the figure. The work done by the system along the paths $a f,ib$ and $bf$ are $W _{ af }=200 \,J , W _{ ib }=50 \,J$ and $W _{ bf }=100\, J$ respectively. The heat supplied to the system along the path iaf, $ib$ and $bf$ are $Q _{ \text{iaf}}$, $Q _{\text{ib }}$ and $Q _{\text {bf }}$ respectively. If the internal energy of the system in the state $b$ is $U _{ b }=200 \,J$ and $Q _{\text {iaf }}=500 \,J$, the ratio $Q _{\text{bf}} / Q _{\text{ib}}$ isPhysics Question Image

JEE AdvancedJEE Advanced 2014Thermodynamics

Solution:

$U _{ b }=200\, J ,$
$ U _{ i }=100\, J$
Process iaf
Process W(in Joule) $\Delta U$ ( in Joule )s Q(in Joule)
ia 0
af 200
Net 300 200 500

$\Rightarrow U _{ f }=400$
Joule Process ibf
Process W(in Joule) $\Delta U$ ( in Joule ) Q(in Joule)
ib 100 50 150
bf 200 100 300
Net 300 150 450