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Q. A compound contains $4.07 \%$ hydrogen, $24.27 \%$ carbon and $71.65 \%$ chlorine. Its molar mass is $98.96 \,g \,mol^{-1}$. What will be the molecular formula of the substance?

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Solution:

Element % of Element Relative number of mole
H 4.07 $\frac{4.07}{1} = 4.07 \approx 4$
C 24 . 27 $\frac{24.27}{12} \approx 2$
Cl 71 .65 $\frac{71 . 65}{35.5} \approx 2$

$\therefore $ Empirical formula $= C_2H_4Cl_2$