Q.
Write the chemical equations involved in the extraction of lead from galena by self reduction process.
2010
185
IIT JEEIIT JEE 1979General Principles and Processes of Isolation of Elements
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Solution:
In the first step, galena is heated in presence of O2 (limited quantity) in a reverberatory furnace, where PbS is partially oxidised to PbO : PbS+23O2→PbO+SO2
In the second step, more PbS is added and heated in absence of O2, where the following self reduction takes place PbS+2PbO→3Pb+SO2