Q.
Within the list shown below, the correct pair of structures of alanine in pH ranges 2−4 and 9−11 is
(I) H3N+−CH(CH3)CO2H
(II) H2N−CH(CH3)CO2−
(II) H3N+−CH(CH3)CO2−
(IV) H2N−CH(CH3)CO2H
Isoelectric point for neutral amino acids ranges from pH5.5 to 6.3. Acidic amino acids have isoelectric point around 3 while basic amino acids have ranges from pH7.6 to 10.8.
At isoelectric point, amino acids exist as Zwitter ions. At low pH, it exists as cation and at high pH, it exists as anion. Hence, alanine (pH range 2−4) will exist as cation while alanine (pH range 9−11 ) will exist as anion.
Acidic medium: H3N+−CH(CH3)CO2H
Basic medium: H2N−CH(CH3)CO2−