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Question
Chemistry
Which type of graph gives straight line in langmuir adsorption isotherm?
Q. Which type of graph gives straight line in langmuir adsorption isotherm?
1800
188
Surface Chemistry
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A
m
x
→
P
1
B
x
m
→
P
1
C
lo
g
10
m
x
→
P
1
D
lo
g
10
m
x
→
P
Solution:
m
x
=
1
+
b
p
a
p
This equation is known as Lagmuir adsorption isotherm. where;
x
=
mass of gas adsorbed
m = grams of the adsorbent and a and b are constants.
Taking reciprocal of both sides, we have
x
m
=
a
p
1
+
b
p
x
m
=
a
p
1
+
a
b
Thus; a plot of
x
m
versus
p
1
will be straight line.