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Q. Which type of graph gives straight line in langmuir adsorption isotherm?

Surface Chemistry

Solution:

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$\frac{x}{m}=\frac{a p}{1+b p}$

This equation is known as Lagmuir adsorption isotherm. where; $x=$ mass of gas adsorbed

m = grams of the adsorbent and a and b are constants.

Taking reciprocal of both sides, we have

$\frac{ m }{ x }=\frac{1+ bp }{ ap }$

$\frac{ m }{ x }=\frac{1}{ ap }+\frac{ b }{ a }$

Thus; a plot of $\frac{ m }{ x }$ versus $\frac{1}{ p }$ will be straight line.