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Question
Chemistry
Which sets of the d- orbitals are directly oriented towards the ligands in octahedral coordination compounds?
Q. Which sets of the d- orbitals are directly oriented towards the ligands in octahedral coordination compounds?
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TS EAMCET 2020
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A
d
x
2
−
y
2
and
d
x
y
B
d
z
2
and
d
yz
C
d
x
z
and
d
x
y
D
d
x
2
−
y
2
and
d
z
2
Solution:
d
-subshell has five orbitals, i.e.
d
x
2
−
y
2
⋅
d
z
2
,
d
x
y
′
d
x
z
and
d
y
z
∗
.
Out of which
d
x
2
−
y
2
and
d
z
2
are directly oriented towards ligands in octahedral coordination compounds because of high electron density in its orbitals.