Q. Which one of the following is not an ideal solution?

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Solution:

An ideal solution is one which possesses following characters
(i) obeys Raoult's law
(ii)
(iii)
(iv) Mole fraction = active mass,
Similar, liquid pairs (like benzene + toluene, -hexane + -heptane, mixture, mixture, mixture etc.) form ideal solution.
So, mixture is not an ideal solution.
Because this does not obey the above rule and fact hence, form non-ideal solution.