Q.
Which one of the following has the smallest bond angle ?
3800
189
KEAMKEAM 2003Chemical Bonding and Molecular Structure
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Solution:
Hybridisation involved in NH3 is sp3 with one lone pair, in BeF2 is sp2 with no lone pair, in H2O is sp3 with two lone pairs, in CH4 is sp3
with no lone pair, in SO2 is sp1 with one lone pair. Therefore, least bond angle is H2O (= 104-5∘).