Q. Which one of the following compounds has the most acidic nature?

 3830  173 AIPMTAIPMT 2010Alcohols Phenols and Ethers Report Error

Solution:

Presence of electron withdrawing substituent increases the acidity while electron releasing substituent, when present, decreases the acidity.
Phenyl is an electron withdrawing substituent while is an electron releasing substituent.
Moreover, phenoxide ion is more resonance stabilised as compared to benzyloxide ion, thus releases proton more easily. That's why phenol is a strong acid among the given compounds