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Question
Chemistry
Which one of the following carbonyl compounds cannot be prepared by addition of water on an alkyne in the presence of HgSO 4 and H 2 SO 4 ?
Q. Which one of the following carbonyl compounds cannot be prepared by addition of water on an alkyne in the presence of
H
g
S
O
4
and
H
2
S
O
4
?
4225
199
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Aldehydes Ketones and Carboxylic Acids
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A
12%
B
30%
C
50%
D
8%
Solution:
Reaction of
H
g
S
O
4
/
d
i
l
.
H
2
S
O
4
with alkyne gives addition of water as per markonikoff's rule.
Hence
C
H
3
−
C
H
2
−
C
H
O
cannot be form.