Q.
Which one among the following is most reactive towards electrophilic substitution reaction?
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J & K CETJ & K CET 2011Hydrocarbons
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Solution:
The rate of electrophilic substitution reaction is directly proportional to nucleophilicity of Benzene ring. The group which increase the electron density in benzene ring i.e. electron donating group increase the nucleophilicity of Benzene ring which results in an increase in the rate of reaction towards electrophilic substitution Rnn. In series of activating group OH comes first then OCH3, hence, phenol is most reactive towards electrophilic substitution reaction.