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Tardigrade
Question
Chemistry
Which of the statements are WRONG about the nucleophilic addition reaction of alkenes and alkynes?
Q. Which of the statements are WRONG about the nucleophilic addition reaction of alkenes and alkynes?
72
156
Hydrocarbons
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A
Addition of nucleophile
(
R
O
⊖
)
to an alkene gives an alkyl carbanion
whose negative charge is on the
s
p
3
-hydridised
C
atom
B
Addition of nucleophile
(
R
O
⊖
)
to an alkyne gives a vinyl carbanion
whose negative charge is on the
s
p
2
-hybridized
C
atom. Due to more
s
character, it is readily formed and more stable than alkyl carbanion formed with alkenes. So alkynes are more reactive than alkenes towards NA reaction
C
Strong electron-withdrawing inductive effect (-I) further stabilizes both vinyl and alkyl carbanion
D
Strong electron-donation inductive effect
(
+
I
)
further stabilises both vinyl and alkyl carbanion
Solution:
Statements are self explanatory