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Chemistry
Which of the statements are WRONG about the nucleophilic addition reaction of alkenes and alkynes?
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Q. Which of the statements are WRONG about the nucleophilic addition reaction of alkenes and alkynes?
Hydrocarbons
A
Addition of nucleophile $( R \overset{\ominus}{O} )$ to an alkene gives an alkyl carbanion
whose negative charge is on the $s p^3$-hydridised $C$ atom
B
Addition of nucleophile $( R\overset{\ominus}{O} )$ to an alkyne gives a vinyl carbanion
whose negative charge is on the $s p^2$-hybridized $C$ atom. Due to more $s$ character, it is readily formed and more stable than alkyl carbanion formed with alkenes. So alkynes are more reactive than alkenes towards NA reaction
C
Strong electron-withdrawing inductive effect (-I) further stabilizes both vinyl and alkyl carbanion
D
Strong electron-donation inductive effect $(+ I )$ further stabilises both vinyl and alkyl carbanion
Solution:
Statements are self explanatory