Q.
Which of the following will give carbylamines reaction?
2797
196
Rajasthan PETRajasthan PET 2002
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Solution:
Primary amine reacts with chloroform and alcoholic solution of KOH to form bad smell compound of isocyanide. This reaction is called carbylamine reaction. methylamineCH3NH2+CHCl3+3KOHmethylisocyanideCH3NC+3KCl+3H2O