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Question
Chemistry
Which of the following statement about anhydrous aluminum chloride is correct?
Q. Which of the following statement about anhydrous aluminum chloride is correct?
296
175
NTA Abhyas
NTA Abhyas 2022
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A
It fumes in moist air.
B
It exists as dimer both in the vapor state below
35
0
∘
C
and in non-polar solvents
C
It is prepared by heating
A
l
2
O
3
in a stream of Sulphur chloride (
S
2
C
l
2
) vapor and chlorine.
D
All of these
Solution:
(i)
A
lC
l
3
+
3
H
2
O
→
A
lO
H
3
+
3
H
Cl
↑
fumes
(ii) It exists as dimer in non-polar solvents like benzene and in vapour state below
35
0
∘
C
.
(iii)
4
A
l
2
O
3
+
3
S
2
C
l
2
+
9
C
l
2
→
8
A
lC
l
3
+
6
S
O
2
↑
A
,
B
,
C
are correct
D