In cannizaro reaction C−C cannot be formed as here the compound (aldehyde) having no α−H− atom undergoes disproportion with a strong base to give an alcohol and an acid salt for eg. 2HCHO→conc.NaOHHCOONa+CH3OH
While in all other reactions C-C bond formation occur. Friedal- Crafts acylation:- Reimer- Tieman reaction:- Wurtz reaction:-