Unit less physical quantities are always dimensionless. For example, refractive index and relative density. These quantities are the ratio of same physical quantities.
A dimensionless physical quantity may have a unit. For example, plane angle and solid angle. The unit of plane angle is radian but it is dimensionless.
Now, Coefficient of friction=Normal reactiomfriction force =[MLT−2][MLT−2] = no dimensions
Unit= NN = no unit
The coefficient of friction is the ratio of two forces. Hence, it is dimensionless. It also don't have any unit.