Q. Which of the following orders regarding ionization energy is correct ?

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Solution:

Ionisation energy is the energy required to remove an electron from outer shell of an atom. Since, on moving from left to right in a period, size decreases, thus, larger amount of energy is required to remove an electron, ie, ionisation energy increases.
Although the size of atom is smaller as compared to but the ionisation energy of is higher. This is because in case of , the electron is to be removed from half-filled orbital. Thus, the order of ionisation energy is