Which of the following order of basic strength is correct?

Question

Which of the following order of basic strength is correct? (A) NH3 < NH2 OH < HN3 < NH2-NH2 (B) NH2 OH < HN3 < NH2-NH2 < NH3 (C) HN3 < NH3 < NH2 OH < NH2 -H2 (D) HN3 < NH2 OH < NH2-NH2 < NH3

Tardigrade Admin · Accepted Answer

Basicity in nitrogen compounds is attributed to the availability of lone pair of electrons. The order of availability of

e^{-}

pair on

N

-atom is

N H_{3} > N H_{2} - N H_{2} > H N_{3} > N H_{2} O H

Therefore, same is the order of basicity of these compounds.

Q. Which of the following order of basic strength is correct?

$N H_{3} < N H_{2} O H < H N_{3} < N H_{2} - N H_{2}$

$N H_{2} O H < H N_{3} < N H_{2} - N H_{2} < N H_{3}$

$H N_{3} < N H_{3} < N H_{2} O H < N H_{2} - H_{2}$

$H N_{3} < N H_{2} O H < N H_{2} - N H_{2} < N H_{3}$

Basicity in nitrogen compounds is attributed to the availability of lone pair of electrons. The order of availability of $e^{-}$ pair on $N$ -atom is

$N H_{3} > N H_{2} - N H_{2} > H N_{3} > N H_{2} O H$

Therefore, same is the order of basicity of these compounds.

Q. Which of the following order of basic strength is correct?

NH3​<NH2​OH<HN3​<NH2​−NH2​

NH2​OH<HN3​<NH2​−NH2​<NH3​

HN3​<NH3​<NH2​OH<NH2​−H2​

HN3​<NH2​OH<NH2​−NH2​<NH3​

Basicity in nitrogen compounds is attributed to the availability of lone pair of electrons. The order of availability of e− pair on N-atom is NH3​>NH2​−NH2​>HN3​>NH2​OH Therefore, same is the order of basicity of these compounds.

$N H_{3} < N H_{2} O H < H N_{3} < N H_{2} - N H_{2}$

$N H_{2} O H < H N_{3} < N H_{2} - N H_{2} < N H_{3}$

$H N_{3} < N H_{3} < N H_{2} O H < N H_{2} - H_{2}$

$H N_{3} < N H_{2} O H < N H_{2} - N H_{2} < N H_{3}$

Basicity in nitrogen compounds is attributed to the availability of lone pair of electrons. The order of availability of $e^{-}$ pair on $N$ -atom is

$N H_{3} > N H_{2} - N H_{2} > H N_{3} > N H_{2} O H$

Therefore, same is the order of basicity of these compounds.