Q.
Which of the following is not isostructural with SiCl4 ?
4170
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AIPMTAIPMT 2006Chemical Bonding and Molecular Structure
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Solution:
SCl4 is not isostructural with SiCl4 because shows square planar structure due to involvement of repulsion between lone pair and bond pair of electrons. SO42− shows tetrahedral structure due to sp3 hybridisation. PO43− shows tetrahedral structure due to sp3 hybridisation. NH4+ shows tetrahedral structure due to sp3 hybridisation.