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Question
Chemistry
Which of the following is not a physical equilibrium ?
Q. Which of the following is not a physical equilibrium ?
1348
218
UPSEE
UPSEE 2009
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A
Ice
⇌
Water
B
I
2
(
s
)
⇌
I
2
(
g
)
C
S
(
l
)
⇌
S
(
g
)
D
3
O
2
⇌
2
O
3
Solution:
When a compound or element exists in different phases (states), a physical equilibrium exists between them.
(a)
(solid state of
H
2
O
)
Ice
(liquid state of
H
2
O
)
Water
(physical equilibrium)
(b)
I
2
(
s
)
⇌
I
2
(
g
)
(physical equilibrium)
(c)
S
(
l
)
⇌
S
(
g
)
(physical equilibrium)
(d)
3
O
2
(
g
)
⇌
2
O
3
(
g
)
O
2
and
O
3
are the allotropes of oxygen, ie, have different composition, so the equilibrium exist between them is considered as chemical equilibrium.