Wilkinson's catalyst is [RhCl(PPh3)3], Red-violet in colour and has square planar structure. It is used for selective hydrogenation of organic molecules at room temperature and pressure.
TiCl4 + (C2H5)3 Al is Zeigler Natta catalyst.
(C2H5)4)Pb is an anti-knocking agent.
cis-platin is used as anti-cancer agent.