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Question
Chemistry
Which of the following is (are) correct for buffer solution?
Q. Which of the following is (are) correct for buffer solution?
261
142
Equilibrium
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A
Acidic buffer will be effective within in the
p
H
range
(
p
K
a
±
1
)
B
Basic buffer will be effective within the
p
H
range
(
p
K
w
−
p
K
b
±
1
)
C
H
3
P
O
4
+
N
a
H
2
P
O
4
is not a buffer solution
D
Buffers behave most effectively when the [Salt]/[Acid] ratio equal to 1
Solution:
For acidic buffer, buffer capacity is maximum at
p
H
=
p
K
a
and for basic buffer, it is maximum at
p
H
=
p
K
w
−
p
K
b
. Buffer is always effective within a
p
H
range of
1
with respect to the
p
H
at maximum buffer capacity
H
3
P
O
4
+
H
2
P
O
4
⊖
is a buffer solution