Disproportionation redox reaction involves simultaneous oxidation and reduction of atoms of same element from one oxidation state to two different oxidation states. 2NO2+4(g)+2OH−→NO2−+3+NO3−+5+H2O
In this reaction, N of nitrogen dioxide is of +4 oxidation state but after the reaction, N is present in +3 and +5 oxidation state simultaneously. So, this reaction is an example of disproportionation redox reaction.