Which of the following have distorted octahedral structure?

Question

Which of the following have distorted octahedral structure? (A) SF6 (B) PF6 ominus (C) SiF62- (D) XeF6

Tardigrade Admin · Accepted Answer

<img class="img-fluid question-image" alt="image" src="https://cdn.tardigrade.in/img/question/chemistry/e7bb6a3f2643c6cb19132077ddea669c-.jpeg" /> AB6 E type (:XeF6) have sp3 d3 hybridisation with TBP geometry and it should have pentagonal pyramid shape. But this case is an exception in which it has distorted structure.

Q. Which of the following have distorted octahedral structure?

$S F_{6}$

$P F_{6}^{⊖}$

$S i F_{6}^{2 -}$

$X e F_{6}$

$A B_{6} E$ type $(: X e F_{6})$ have $s p^{3} d^{3}$ hybridisation with $TBP$ geometry and it should have pentagonal pyramid shape.
But this case is an exception in which it has distorted structure.

Q. Which of the following have distorted octahedral structure?

SF6​

PF6⊖​

SiF62−​

XeF6​

AB6​E type (:XeF6​) have sp3d3 hybridisation with TBP geometry and it should have pentagonal pyramid shape. But this case is an exception in which it has distorted structure.

$S F_{6}$

$P F_{6}^{⊖}$

$S i F_{6}^{2 -}$

$X e F_{6}$

$A B_{6} E$ type $(: X e F_{6})$ have $s p^{3} d^{3}$ hybridisation with $TBP$ geometry and it should have pentagonal pyramid shape.
But this case is an exception in which it has distorted structure.