Q. Which of the following exists ?

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Solution:

has tendency to form
Fluorine is highly electronegative. Therefore, fluorine atom has a strong tendency to attract electrons. seven fluorine does not create a crowd surrounding the manganese atoms. Hence is not stable.
As is a stronger reducing agent, i.e. reductant, and reduces into and Itself is oxidized into ​. Therefore, does not.
in and less crowded surrounding cental metal hence, it is stable.