As ‘n’ increases the difference in energy between successive orbits decreases
From n=1 to n=2, difference in energy, ΔE=E2−E1=10.2eV
From n=1 to n=∞, ΔE=E∞−E1=0−(13.6)=13.6eV ∴ From n=2 to any higher stationary state, ΔE≤(13.6−10.2=3.4eV)
In option (1) and (4), energy is released