Which of the following are the incorrect conversion of acetone into acetamide?

Question

Which of the following are the incorrect conversion of acetone into acetamide? (A) CH 3 COCH 3 xrightarrow Pd / BaSO 4 CH 3 CHO xrightarrow NH 3CH 3 CH 2 NH 2 xrightarrow H 2 O CH 3 CONH 2 (B)  (C) CH 3 COCH 3 xrightarrow CrO 3 CH 3 COOH xrightarrow NH 3CH 3 CONH 2 (D) CH 3 COCH 3 xrightarrow I 2 / NaOH CH 3 COOH xrightarrow HCl CH 3 COCl xrightarrow NH 3 CH 3 CONH 2

Tardigrade Admin · Accepted Answer

a, c, d are incorrect. Only (b) is correct, i.e. underset text Acetone CH 3 COCH 3 xrightarrow I 2 / NaOH underset text Sodium acetate CH 3 COONa xrightarrow[ NH 3] H + underset textAcetamideCH 3 CONH 2 xleftarrowΔ underset textAmmonium acetateCH 3 CO overset-O overset+NH 4

Q. Which of the following are the incorrect conversion of acetone into acetamide?

$C H_{3} COC H_{3} P d / B a S O_{4} C H_{3} C H O N H_{3} C H_{3} C H_{2} N H_{2} H_{2} O C H_{3} CON H_{2}$

$C H_{3} COC H_{3} C r O_{3} C H_{3} COO H N H_{3} C H_{3} CON H_{2}$

$C H_{3} COC H_{3} I_{2} / N a O H C H_{3} COO H H Cl C H_{3} COCl N H_{3} C H_{3} CON H_{2}$

$a, c, d$ are incorrect. Only (b) is correct, i.e.
$Acetone C H_{3} COC H_{3} I_{2} / N a O H Sodium acetate C H_{3} COON a H^{+} N H_{3}$
$Acetamide C H_{3} CON H_{2} Δ Ammonium acetate C H_{3} CO O - N + H_{4}$

Q. Which of the following are the incorrect conversion of acetone into acetamide?

CH3​COCH3​Pd/BaSO4​​CH3​CHONH3​​CH3​CH2​NH2​H2​O​CH3​CONH2​

CH3​COCH3​CrO3​​CH3​COOHNH3​​CH3​CONH2​

CH3​COCH3​I2​/NaOH​CH3​COOHHCl​CH3​COClNH3​​CH3​CONH2​

a,c,d are incorrect. Only (b) is correct, i.e. Acetone CH3​COCH3​​I2​/NaOH​ Sodium acetate CH3​COONa​H+NH3​​ AcetamideCH3​CONH2​​Δ​Ammonium acetateCH3​COO−N+H4​​

$C H_{3} COC H_{3} P d / B a S O_{4} C H_{3} C H O N H_{3} C H_{3} C H_{2} N H_{2} H_{2} O C H_{3} CON H_{2}$

$C H_{3} COC H_{3} C r O_{3} C H_{3} COO H N H_{3} C H_{3} CON H_{2}$

$C H_{3} COC H_{3} I_{2} / N a O H C H_{3} COO H H Cl C H_{3} COCl N H_{3} C H_{3} CON H_{2}$

$a, c, d$ are incorrect. Only (b) is correct, i.e.
$Acetone C H_{3} COC H_{3} I_{2} / N a O H Sodium acetate C H_{3} COON a H^{+} N H_{3}$
$Acetamide C H_{3} CON H_{2} Δ Ammonium acetate C H_{3} CO O - N + H_{4}$