Q.
Which is the least stable carbocation?
I. CH3CH2C+H2
II. CH3C+HCH3
III. (CH3)4C+
VI. (CH3)3CC+H2
3197
178
AMUAMU 2014Organic Chemistry – Some Basic Principles and Techniques
Report Error
Solution:
Stability of carbocation depends upon the number of hyperconjugative structures. More the hyperconjugative structure (i.e., more the number of hydrogen atoms attached directly to a-carbon atom), more is the stability of carbocation
Thus, the order of stability of given carbocation is
Thus, (CH3)3CCH2+(IV) is least stable carbocation among the given