Washing soda is sodium carbonate decahydrate (Na2CO3⋅10H2O). It is an efflorescent substance i.e., give out nine water molecules of crystallization on keeping in air Na2CO3⋅10H2O air Sodium carbonate monohydrateNa2CO3⋅H2O+9H2O
But on heating it losses all water molecules to form anhydrous sodium carbonate or soda ash Na2CO3⋅10H2OΔ(Soda ash)Na2CO3+10H2O