When hydrochloric acid gas is treated with propene in presence of benzoyl peroxide, it gives

Question

When hydrochloric acid gas is treated with propene in presence of benzoyl peroxide, it gives (A) 2-chloropropane (B) allyl chloride (C) no reaction (D) n-propyl chloride

Tardigrade Admin · Accepted Answer

Peroxide effect is observed only in case of HBr. Therefore, addition of HCl to propene even in the presence of benzoyl peroxide occurs according to Markownikoffs rule. CH3CH=CH2 xrightarrow[(C6H5COO)2]HClCH3-CHCl-CH3

Q. When hydrochloric acid gas is treated with propene in presence of benzoyl peroxide, it gives

2-chloropropane

allyl chloride

no reaction

n-propyl chloride

Peroxide effect is observed only in case of HBr. Therefore, addition of $H Cl$ to propene even in the presence of benzoyl peroxide occurs according to Markownikoffs rule. $C H_{3} C H = C H_{2} H Cl (C_{6} H_{5} COO)_{2} C H_{3} - C H Cl - C H_{3}$

Q. When hydrochloric acid gas is treated with propene in presence of benzoyl peroxide, it gives

2-chloropropane

allyl chloride

no reaction

n-propyl chloride

Peroxide effect is observed only in case of HBr. Therefore, addition of HCl to propene even in the presence of benzoyl peroxide occurs according to Markownikoffs rule. CH3​CH=CH2​HCl(C6​H5​COO)2​​CH3​−CHCl−CH3​

Peroxide effect is observed only in case of HBr. Therefore, addition of $H Cl$ to propene even in the presence of benzoyl peroxide occurs according to Markownikoffs rule. $C H_{3} C H = C H_{2} H Cl (C_{6} H_{5} COO)_{2} C H_{3} - C H Cl - C H_{3}$