When aniline is nitrated with nitrating mixturte in ice cold condition, the major product obtained is

Question

When aniline is nitrated with nitrating mixturte in ice cold condition, the major product obtained is (A) p-nitroaniline (B) 2,4-dinitroaniline (C) o-nitroaniline (D) m-nitroaniline

Tardigrade Admin · Accepted Answer

Direct nitration of aniline with nitric acid gives a complex mixture of mono, di- and tri-nitro compounds and oxidation products. If - NH 2 group is protected by acetylation and then nitrated with nitrating mixture, p-isomer is the main product. <img class="img-fluid question-image" alt="image" src="https://cdn.tardigrade.in/img/question/chemistry/f56abbf2e7beebcd77c931230084a6d6-.png" />

Q. When aniline is nitrated with nitrating mixturte in ice cold condition, the major product obtained is

$p$ -nitroaniline

$2, 4$ -dinitroaniline

$o$ -nitroaniline

$m$ -nitroaniline

Direct nitration of aniline with nitric acid gives a complex mixture of mono, di- and tri-nitro compounds and oxidation products. If $- N H_{2}$ group is protected by acetylation and then nitrated with nitrating mixture, $p$ -isomer is the main product.

Q. When aniline is nitrated with nitrating mixturte in ice cold condition, the major product obtained is

p-nitroaniline

2,4-dinitroaniline

o-nitroaniline

m-nitroaniline

Direct nitration of aniline with nitric acid gives a complex mixture of mono, di- and tri-nitro compounds and oxidation products. If −NH2​ group is protected by acetylation and then nitrated with nitrating mixture, p-isomer is the main product.

$p$ -nitroaniline

$2, 4$ -dinitroaniline

$o$ -nitroaniline

$m$ -nitroaniline

Direct nitration of aniline with nitric acid gives a complex mixture of mono, di- and tri-nitro compounds and oxidation products. If $- N H_{2}$ group is protected by acetylation and then nitrated with nitrating mixture, $p$ -isomer is the main product.