We know that momentum of a photon, p=λh ⇒mv=λh⇒v=mλh..(i) [∵p=mv]
Given, hydrogen atom emits a photon during a transition from n=4 to n=2, According to Bohr's formula for H -atom, the wavelength of the emitted photon is given by ∴λ1=R(n121−n221)
where, R= Rydberg's constant =1.097×107m−1 ⇒λ1=1.097×107(221−421) ⇒λ=4.86×10−7m ∵ Mass of a proton =1.6×10−27kg
Now, from Eq. (i), we get
Hence, recoil speed of photon, v=1.6×10−27×4.86×10−76.62×10−34 =0.8513m/s
or v≈0.814ms−1