For a Balmer series λB1=R[221−n21]...(i)
where n=3,4,.....
By putting n=∞ in equation (i), we obtain the series limit of the Balmer series. This is the shortest wavelength of the Balmer series.
or λB=R4...(ii)
For a Lyman series λL1=R[121−n21]...(iii)
where n=2,3,4,....
By putting n=∞ in equation (iii), we obtain the series limit of the Lyman series. This is the shortest wavelength of the Lyman series.
or λL=R1...(iv)
Dividing (ii) by (iv), we get λLλB=14