At STP condition, the volume at STP is 22.4L .
Now, the 5.6L of alkane has weigh 11g at STP
Then, 1g of alkane has weight of 22.4LSTP is =5.6L11g×22.4L ⇒44gm
The molecular mass of alkane at STP is 44gm .
So, C3H8 has molecular mass if M=nw . C3H8=3×12+8×1 ⇒36+8 ⇒44u