Free body diagram (FBD) of the block (shown by a dot) is shown in figure.
For vertical equilibrium of the block, N=mg+Fsin60∘=3g+32F….(i)
For no motion, force of friction f≥Fcos60∘
or ∘μN≥Fcos60∘
or 231(3g+23F)≥2F
or g≥2ForF≤2gor20N
Therefore, maximum value of F is 20N.