Q.
Two oxides of a metal contain 36.4% and 53.4% of oxygen by mass respectively. If the formula of the first oxide is M2O, then that of the second is
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J & K CETJ & K CET 2011Some Basic Concepts of Chemistry
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Solution:
For I oxide Oxygen =36.4%
Metal =100−36.4=63.6
Given, formula of oxide =M2O ∴63.6% of metal =2 atoms of metal
and 36.4% of oxygen =1 atom of oxygen For II oxide Oxygen =53.4%
Metal =100−53.4=46.6% ∵63.6% of metal =2 atoms of metal ∴46.6% of metal =63.62×46.6 =1.46 atoms of metal Again ∵36.4% of oxygen =1 atom of oxygen ∴53.4% of oxygen =36.41×53.4 =1.46 atoms of oxygen Ratio of metal and oxide =1.46:1.46 =1:1
Hence, formula of metal oxide =MO