Q.
Two electrons in two hydrogen-like atoms A and B have their total energies EA and EB in the ratio EA:EB=1:2 . Their potential energies UA and UB are in the ratio UA:UB=1:2 . If λA and λB are their de-Broglie wavelengths, then λA:λB is
Given, EBEA=21,UBUA=21
So EA=x,EB=2x
And UA=y,UB=2y ∵EA=UA+KA
And EB=UB+KB
here KA and KB are kinetic energy of particles A and B
So KA=EA−UA=(x−y)….. (i) KB=EB−UB=2(x−y)…. (ii) ∵ de-Broglie wavelength, λ=2mkh
So λA=2mKAh,λB=2mKBh ∴λBλA=KAKB…… (iii)
From Equation (i), (ii) and (iii), λBλA=(x−y)2(x−y)=12