Q.
Two chamber containing m1 and m2 grams of a gas at pressures P1 and P2 respectively are put in communication with each other, temperature remaining constant. The common pressure reached will be
According to Boyles law, PV=kT (a constant)
or Pρm=kT orρ=kTPm
orρ=KP (where mkT=K a constant)
So, ρ1=KP1 and V1=ρ1m1=P1/Km1=P1Km1
Similarly, V2=P2Km2
Total volume =V1+V2=K(P1m1+P2m2)
Let P be the common pressure and ρ be the common density of mixture. Then. ρ=V1+V2m1+m2=K(P1m1+P2m2)m1+m2 ∴P=Kρ=P1m1+P2m2m1+m2=(m1P2+m2P1)P1P2(m1+m2)